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CERAMIC ADHESIVE
CONSIDERATIONS
THERMAL EXPANSION
Hottec offers a wide range of Ceramic Adhesives. This results from
the wide range of materials and conditions that the materials will be
subject too. The major consideration will be the extreme temperature
range as well as the brittle nature of ceramics. There are tremendous
forces generated when a material expands over a large temperature range.
Conventional adhesives need only be concerned with temperature
fluctuation in the normal environmental range of 150 to 200 °
F. additionally most are organics with high flexural strength. Ceramics
must endure fluctuations of up to 4000 °F so
that great changes in dimensions take place. The solution is to have
materials with similar coefficients of thermal expansion. This will
include both the 2 materials being joined but also the expansion of the
adhesive material itself. Please review the thermal expansion of your
materials on the <<link Thermal Expansion Tables>>, which
has common materials as well as our adhesives. These materials will
change dimensions together thus minimizing the stress. If it is not
possible to use materials of very close thermal expansion properties it
would be an advantage to pick an adhesive with expansions midway between
the 2 or perhaps change or introduce a third component with middle
properties so that the stress is spread over more than one joint.
ENVIRONMENTAL FACTORS
The other main selection criteria are the environment that the joint
will be placed in and the changes, which may have to endure. There are
some ceramic adhesives that are stronger at a continuous 2000°F
then at room temperature. Atmospheric considerations such as moisture,
acid, or alkaline, vacuum or corrosive gasses can all attack the
adhesive joint. Look for the adhesive that tolerates the conditions that
will exist for the parts. Thermal cycling to room temperature and back
up such as in firing operations will also expose the joint to air and
potential moisture absorbance. This atmospheric moisture will have to be
driven off prior to exposure to high heat. The data screens will have
pertinent information about what this material can tolerate.
CURING
Lastly to select what adhesive to use will be its requirement for
curing. Most of these materials have to 2 types of moisture in them.
There is the free water that is what makes them a liquid and also waters
of solution and crystallization. Many ceramics actually have water as
part of their crystal make-ups. These waters usually have to be driven
off before the joint is taken to higher temperatures. Therefore most
ceramic materials have a 2 stage curing procedure where by the free
water is eliminated at a below water boiling point of 212°F
by simple air-drying in an oven. Next there is a higher heat cure where
the molecular crystal water is driven off at a higher temperature. This
will cure most of the materials and make the joint moisture resistant,
however if the joint has been soaked in water some gentle drying may be
required so that steam generated will not force the joint apart. |