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BONDCERAM 311
MATERIAL SAFETY DATA SHEET
HOTTEC CORP.
Material Safety Data Sheet
1 CHEMICAL PRODUCT AND COMPANY DESCRIPTION
Hottec Corp.
One Terminal Way
Norwich , Ct 06360
Emergency Phone Numbers:
For emergencies involving a spill, leak, fire, exposure, or accident
Contact: Hottec Corp. 860-887-5111, EMERGENCY evenings 860-822-1701
For Product Information:
860-887-5111
Chemical Name or Synonym:
BONDCERAM 311
2 COMPOSITION/INFORMATION ON INGREDIENTS
OSHA
Component CAS Reg Number Hazard Percentage
PHOSPHATE ACID SALT 13530-50-2 Y 50
WATER 7732-18-5 N Balance
INERT FILLER
3 HAZARDS IDENTIFICATION
A. Emergency Overview:
Physical Appearance and Odor:
White pasty/ liquid, odorless.
Warning Statements:
Danger! Causes Burns.
B. Potential Health Effects:
Acute Eye:
Corrosive. Causes burns.
Acute Skin:
Causes irritation, May cause burns.
Acute Inhalation:
Mists may cause upper respiratory tract irritation.
Acute Ingestion:
May cause nausea, vomiting, diarrhea, irritation, burns to mouth and
esophagus.
Chronic Effects:
This product does not contain any ingredient designated by IARC, NTP,
ACGIH or OSHA as probable or suspected human carcinogens.
4 FIRST AID MEASURES
First aid measures for accidental:
Eye exposure:
Hold eyelids open and flush with a steady, gentle stream of water for
at least 15 minutes. Seek immediate medical attention, preferably with
an ophthalmologist. If the physician is not immediately available, eye
irrigation should be continued for an additional 15 minutes. If it is
necessary to transport the patient to a physician and the eye needs to
be bandaged, use a dry sterile cloth pad and cover both eyes.
Skin exposure:
Immediately wipe excess material off skin with a dry cloth; then wash
with plenty of soap and water for at least 5 minutes. Seek medical
attention if irritation develops or persists. Remove contaminated
clothing and shoes. Clean contaminated clothing and shoes before re-use
Inhalation:
Remove victim from immediate source of exposure and assure that the
victim is breathing. If breathing is difficult, administer oxygen, if
available. If victim is not breathing, administer CPR (cardio-pulmonary
resuscitation). Seek medical attention.
Ingestion:
If victim is conscious and alert, give 1-2 glasses of water to drink.
Do not give anything by mouth to an unconscious person. Seek immediate
medical attention. Do not leave victim unattended. To prevent aspiration
of swallowed product, lay victim on side with head lower than waist.
Vomiting may occur spontaneously. If vomiting occurs and the victim is
conscious, give water to further dilute the chemical.
Medical conditions possibly aggravated by exposure:
Inhalation of product may aggravate existing chronic respiratory
problems such as asthma, emphysema or bronchitis. Skin contact may
aggravate existing skin disease.
Notes to physician:
All treatments should be based on observed signs and symptoms of
distress in the patient. Consideration should be given to the
possibility that overexposure to materials other than this product may
have occurred.
Ingestion of large quantities of phosphate salts (over 1.0 grams for
an adult) may cause an osmotic catharsis resulting in diarrhea and
probable abdominal cramps. Larger doses such as 4-8 grams will almost
certainly cause these effects in everyone. In healthy individuals most
of the ingested salt will be excreted in the feces with the diarrhea
and, thus, not cause any systemic toxicity. Doses greater that 10 grams
hypothetically may cause systemic toxicity. Treatment should take into
consideration both anionic and cation portion of the molecule. The
following treatments should be considered for the specific grooup9s0 of
phosphate salts found in this product:
--All phosphate salts, except calcium salts, have a hypothetical risk
of hypocalcemia, so calcium levels should be monitored.
--Ammonium salts have a hypothetical risk of ammonia toxicity. In
addition to calcium levels, ammonia and phosphate levels should be
monitored.
--Potassium salts have a hypothetical risk of hyperkalemia which can
cause cardiac arrhythmia. In addition to calcium levels, potassium and
phosphate levels should be monitored. Also consider continuous EKG
monitoring to detect hyperkalemia.
--Sodium salts have a hypothetical risk of hypernatremia. In addition
to calcium levels, sodium and phosphate levels should be monitored.
5 FIRE FIGHTING MEASURES
Fire Hazard Data:
Flash point:
Not applicable
Extinguishing media:
Not combustible. Use extinguishing method suitable for surrounding
fire.
Special fire fighting procedures:
Firefighters should wear NIOSH/MSHA approved positive pressure
breathing apparatus with full face-piece and full acid-resistant
protective clothing. Dike area to prevent runoff and contamination of
water sources. Dispose of fire control water later.
Unusual fire and explosion hazards:
Not combustible.
Hazardous decomposition materials (Under fire conditions):
Oxides of phosphorus
6 ACCIDENTAL RELEASE MEASURES
Evacuation procedures and safety:
Wear appropriate protective gear for the situation. See Personal
Protection information in Section 8.
Containment of spill:
Follow procedure described below under Cleanup and Disposal of Spill.
Cleanup and disposal of spill:
Carefully neutralize spill with soda ash. Clean up residual material
by washing area with water. Exercise caution during neutralization as
considerable heat may be generated.
Environmental and regulatory reporting:
Prevent material from entering public sewer system or any waterways.
Large spills should be handled according to a predetermined plan. For
assistance in developing a plan contact the Technical Service Department
using the Product Information phone number in Section 1.
7 HANDLING AND STORAGE
Minimum/maximum storage temperatures:
No data available
Handling:
Avoid breathing vapors. Avoid direct or prolonged contact with skin
and eyes. Do not ingest.
Storage:
Store in an area that is cool, dry, well ventilated, away from
combustible material, away from ignition sources. Store in tightly
closed containers. Recommended container material: stainless steel (type
316), rubberized steel.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Introductory remarks:
These recommendations provide general guidance for handling this
product. Because specific work environments and material handling
practices vary, safety procedures should be developed for each intended
application. While developing safe handling procedures, do not overlook
the need to clean equipment and piping systems for maintenance and
repairs. Waste resulting from these procedures should be handled in
accordance with Section 13: Disposal Considerations.
Assistance with selection, use and maintenance of worker protection
equipment is generally available from equipment manufacturers.
Exposure guidelines:
Exposure limits represent regulated or recommended worker breathing
zone concentrations measured by validated sampling and analytical
methods, meeting OSHA requirements. The following limits (ADGIH, OSHA
and other) apply to this material, where, if indicated, S=skin and
C=ceiling limit:
Aluminum, /AS AL/, Soluble salts
Notes TWA STEL
ACGIH 2 mg/cu m
OSHA 2 mg/cu m
Engineering Controls:
Where engineering controls are indicated by use conditions or a
potential for excessive exposure exists, the following traditional
exposure control techniques may be used to effectively minimize employee
exposures: local exhaust ventilation at the point of generation
Respiratory protection:
When respirators are required, select NIOSH/MSHA approved equipment
based on actual or potential airborne concentrations and in accordance
with the latest OSA standard (29 CFR 1910.134) and/or ANSI Z88.2
recommendations.
Under normal conditions, in the absence of other airborne
contaminants, the following devices should provide protection from this
material up to the conditions specified by OSHA/ANSI : Air-purifying
(half-mask/full-face) respirator with cartridges/canister approved for
use against acid gases.
Eye/face protection:
Eye and face protection requirements will vary dependent upon work
environment conditions and material handling practices. Appropriate ANSI
Z87 approved equipment should be selected for the particular use
intended for this material.
Eye contact should be prevented through use of chemical safety
glasses with side shields or splash proof goggles. An emergency eye wash
must be readily accessible to the work area. Face contact should be
prevented through use of a face shield.
Skin protection:
Skin contact should be prevented through use of suitable protective
clothing, gloves and footwear, selected with regard for use conditions
and exposure potential. Consideration must be given both to durability
as well as permeation resistance.
Work practice controls:
Personal hygiene is an important work practice exposure control
measure and the following general measures should be taken when working
with or handling this material:
(1) Do not store, use, and/or consume foods, beverages, tobacco
products, or cosmetics in areas where this material is stored.
(2) Wash hands and face carefully before eating, drinking, using
tobacco, applying cosmetics, or using the toilet.
(3) Wash exposed skin promptly to remove accidental splashes of
contact with this material.
9 PHYSICAL AND CHEMICAL PROPERTIES
Physical and chemical properties here represent typical properties of
this product. Contact the business area using the Product Information
phone number in Section 1 for its exact specifications.
Physical appearance:
White pasty /liquid.
Odor:
Odorless.
PH:
2.5 at 1 wt/wt%.
Specific gravity:
1.77 at 15 C (59F)
Water solubility:
Partially Soluble leaves inert fillers
Melting point range:
No data available
Boiling point range:
No data available
Vapor pressure:
No data available
Vapor density:
No data available
10 STABILITY AND REACTIVITY
Chemical stability:
This material is stable under normal handling and storage conditions
described in Section 7.
Conditions to be avoided:
Extreme heat.
Materials/chemicals to be avoided:
Strong bases
The following hazardous decomposition products might be expected:
Decomposition type: thermal
Oxides of phosphorus
Hazardous polymerization will not occur.
Avoid the following to inhibit hazardous polymerization:
Not applicable
11 TOXICOLOGICAL INFORMATION
Acute eye irritation:
Toxicological information and interpretation
Eye-eye irritation, rabbit.
Corrosive
Acute skin irritation:
Toxicological information and interpretation
Skin-skin irritation, rabbit.
Corrosive (24 hr exposure)
Skin-skin irritation, rabbit.
Non-irritating (4 hr exposure)
Acute dermal toxicity:
Toxicological information and interpretation
LD50-Lethal dose 50% of test species, 4640 mg/kg, rabbit.
Acute respiratory irritation:
No test data found for product.
Acute respiratory irritation:
No test data found for product.
Acute oral toxicity:
Toxicological information and interpretation
LD50-Lethal dose 50% of test species, >1000 mg/kg, rat.
LD50-Lethal dose 50% of test species, <4640 mg/kg, rat.
Chronic toxicity:
This product does not contain any substances that are considered
by OSHA, NTP, IARC or ACGIH to be “probable” or “suspected”
human carcinogens.
12 ECOLOGICAL INFORMATION
Ecotoxicological information:
No data found for product.
Chemical fate information:
No data found for product.
13 DISPOSAL CONSIDERATIONS
Waste disposal method:
Chemical additions, processing or otherwise altering this material
may make the waste management information presented in this MSDS
incomplete, inaccurate or otherwise inappropriate. Please be advised
that state and local requirements for waste disposal may be more
restrictive or otherwise different from federal laws and regulations.
Consult state and local regulations regarding the proper disposal of
this material.
EPA hazardous waste - yes
14 TRANSPORTATION INFORMATION
Transportation status:
The listed transportation classification does not address regulatory
variations due to changes in package size, mode of shipment or other
regulatory descriptors.
US department of transportation:
DOT hazard class….8
DOT shipping name:
Corrosive liquid, acidic, inorganic, N.O.S.
DOT technical sipping name:
Aluminum phosphate containing solution
DOT ID number ….UN3264
DOT packing group….III
DOT labels….corrosive
Emergency guide#….60
15 REGULATORY INFORMATION
Federal regulations
TSCA inventory status:
All ingredients of this product are listed on the TSCA Inventory.
SARA title III hazard classes:
Fire hazard - No
Reactive hazard -No
Release of pressure -No
Acute health hazard -Yes
Chronic health hazard -No
SARA extremely hazardous substance (EHS) / CERCLA hazardous
substances
Ingredient CERCLA/SARA RQ SARA ES TPQ
Unlisted hazardous wastes - characteristic of corr 100lbs
osivity
State regulations:
This product does not contain any components that are regulated under
California Proposition 65.
16 OTHER INFORMATION
National fire protection association hazard rating-NFPA®:
3 Health hazard rating-serious
0 Flammability rating-minimal
0 Reactivity rating-minimal
National paint & coating hazardous materials indentification
system-HMIS®
3 Health hazard rating-serious
0 Flammability rating-minimal
0 Reactivity rating-minimal
Reason for revisions:
Conversion to ANSI MSDS format.
Key legend information:
NAV - not available
NAP - not applicable
ND - not determined
ACGIH - American conference of governmental industrial hygienists
OSHA - Occupational safety and health administration
TLV - Threshold limit value
PEL - Permissable exposure limit
TWA - Time weighted average
STEL - Short term exposure limit
NTP - National toxicology program
IARC - International agency for research on cancer
Disclaimer:
The information herein is given in good faith but no warranty,
expressed or implied, is made. |